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Specific Features of the Molecular Structure of A New 3-(Benzo[d]Oxazole-2-Yl)- 1-(2-(1,3,3-Trimethylindoline-2-Ylidene) Ethylidene)Naphthalene-2(1H)-One Zinc Chloride Complex


  • Tkachev V.
  • Utenyshev A.
  • Chernyshov A.
  • Kovalchukova O.
Дата публикации:01.03.2018
Журнал: Journal of Structural Chemistry
БД: Scopus
Ссылка: Scopus

Аннтотация

© 2018, Pleiades Publishing, Ltd. X-ray diffraction is used to determine the structure of a new 3-(benzo[d]oxazole-2-yl)-1-(2-(1,3,3- trimethylindoline-2-ylidene)ethylidene)naphthalene-2(1H)-one zinc chloride complex 1. It is demonstrated that the ligand molecule in complex 1 has a trans–trans–cis conformation in which the indoline nitrogen atom is oriented in the same direction as the chelate ring, which could promote an additional coordination with the complexing atom.


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