Репозиторий Университета

Photoredox generation of the trifluoromethyl radical from borate complexes: Via single electron reduction


  • Smirnov V.
  • Maslov A.
  • Kokorekin V.
  • Korlyukov A.
  • Dilman A.
Дата публикации:04.03.2018
Журнал: Chemical Communications
БД: Scopus
Ссылка: Scopus
Индекс цитирования: 4

Аннтотация

© 2018 The Royal Society of Chemistry. A method for the generation of the CF3 radical from CF3-substituted borate complexes bearing a pyridine-N-oxide ligand is described. Cleavage of the C-B bond occurs via single electron reduction by a Cu(i) photocatalyst activated by visible light.


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